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Hartnett was chosen as one of Teen People magazine's "21 Hottest Stars Under 21" in 1999, Teen People's "25 Hottest Stars under 25", and one of People magazine's "50 Most Beautiful People", both in 2002.
He first came to attention in 1997 for his role as Michael Fitzgerald in the television crime drama series Cracker.
In 2002, he starred in O, an adaptation of William Shakespeare's Othello set in an American high school, as Hugo, the film's version of Iago.
In the early 2000s, Hartnett was approached several times to play the role of Clark Kent/Superman in the early 2000s for a project originally helmed by Brett Ratner, but always turned it down, not wanting to commit to a predicted ten-year role.
Hartnett described the second film as "supernatural, but kind of a western".
He was going to play trumpet player Chet Baker in the film The Prince of Cool, but did not agree with the producer's ideas and left the project.